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  A Chiral Sulfoxide-Based C–H Acid

Höfler, D., Kaupmees, K., Leito, I., & List, B. (2022). A Chiral Sulfoxide-Based C–H Acid. Synlett, 33(1), 45-47. doi:10.1055/a-1695-4516.

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Höfler-Kaupmees-Leito-List.pdf (Publisher version), 368KB
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 Creators:
Höfler, Denis1, Author              
Kaupmees, Karl2, Author
Leito, Ivo2, Author
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              
2University of Tartu, Institute of Chemistry, Ravila 14a, 50411 Tartu, Estonia, ou_persistent22              

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Free keywords: sulfoxide C-H acids; stereogenic sulfur; trifyl groups; strong acid; noncoordinating anions; Brønsted acids
 Abstract: We report the design and synthesis of a strong, chiral, enantiopure sulfoxide-based C–H acid. Single crystal X-ray analysis confirms the proposed structure and its absolute configuration. The new motif shows a high acidity and activity in Brønsted and Lewis acid catalyzed transformations. So far,only little to no enantioselectivities were achieved.

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Language(s): eng - English
 Dates: 2021-09-172021-11-042021-11-122022-01-04
 Publication Status: Published in print
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/a-1695-4516
 Degree: -

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Title: Synlett
  Abbreviation : Synlett
Source Genre: Journal
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Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 33 (1) Sequence Number: - Start / End Page: 45 - 47 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856