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  A Chiral, Dendralenic C–H Acid

Höfler, D., & List, B. (2022). A Chiral, Dendralenic C–H Acid. Synlett, 33(1), 38-39. doi:10.1055/a-1705-9786.

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Höfler-List.pdf (Publisher version), 259KB
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 Creators:
Höfler, Denis1, Author              
List, Benjamin1, Author              
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: dendralenic C-H acids; C3 symmetry; Brønsted and Lewis acid catalysis; binaphthyl backbone; conjugated anion
 Abstract: We report the synthesis of a chiral dendralenic C–H acid, which contains three unsubstituted binaphthyl moieties. This motif and an achiral variant can be made from their corresponding bis(sulfone) precursors in one step. Despite the presence of the enantiopure binaphthyl backbone, the newly designed chiral C–H acid showed only poor enantioselectivity in a Mukaiyama aldol reaction. First attempts toward the synthesis of 3,3′-hexasubstituted binaphthyl-based dendralenic acids are also reported.

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Language(s): eng - English
 Dates: 2021-09-172021-11-052021-11-242022-01-04
 Publication Status: Published in print
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/a-1705-9786
 Degree: -

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Title: Synlett
  Abbreviation : Synlett
Source Genre: Journal
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Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 33 (1) Sequence Number: - Start / End Page: 38 - 39 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856