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  The adsorption site of pyridine on Ni{111} determined by low-energy photoelectron diffraction

Fritzsche, V., Bao, S., Hofmann, P., Polcik, M., Schindler, K.-M., Bradshaw, A. M., et al. (1994). The adsorption site of pyridine on Ni{111} determined by low-energy photoelectron diffraction. Surface Science, 319(1-2), L1-L6. doi:10.1016/0039-6028(94)90559-2.

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 Creators:
Fritzsche, V.1, Author           
Bao, Shining1, Author           
Hofmann, Philip1, Author           
Polcik, Martin1, Author           
Schindler, Karl-Michael2, Author           
Bradshaw, Alexander M.1, Author           
Davis, R.3, Author
Woodruff, D.P.3, Author
Affiliations:
1Fritz Haber Institute, Max Planck Society, ou_24021              
2Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
3Department of Physics, University of Warwick, Coventry CV4 7AL, UK, ou_persistent22              

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 Abstract: The adsorption site of pyridine (C5H5N) on Ni{111} has been investigated by scanned-energy mode photoelectron diffraction using the N 1s core level. It was found that the nitrogen atom adsorbs close to the atop position with an angle of 18° (+ 2° - 4°) between the N-Ni bond and the surface normal. The N-Ni bond length is 1.97 ± 0.03 Å. Since recent X-ray absorption studies show that the π system of the pyridine is also tilted by about 20° away from the surface normal, we conclude that the N-Ni bond and the ring plane are co-planar.

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Language(s): eng - English
 Dates: 1994-07-061994-08-191994-11-01
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0039-6028(94)90559-2
 Degree: -

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Title: Surface Science
  Abbreviation : Surf. Sci.
Source Genre: Journal
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Publ. Info: Amsterdam : Elsevier
Pages: 6 Volume / Issue: 319 (1-2) Sequence Number: - Start / End Page: L1 - L6 Identifier: ISSN: 0039-6028
CoNE: https://pure.mpg.de/cone/journals/resource/0039-6028