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  The Electronic and the Ionic Contribution to the Free Energy of Alkali Metals in Intercalation Compounds

Gerischer, H., Decker, F., & Scrosati, B. (1994). The Electronic and the Ionic Contribution to the Free Energy of Alkali Metals in Intercalation Compounds. Journal of the Electrochemical Society, 141(9), 2297-2300. doi:10.1149/1.2055115.

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Item Permalink: https://hdl.handle.net/21.11116/0000-0009-9CEA-0 Version Permalink: https://hdl.handle.net/21.11116/0000-0009-A8F6-4
Genre: Journal Article

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 Creators:
Gerischer, Heinz1, Author           
Decker, F.2, Author
Scrosati, B.2, Author
Affiliations:
1Fritz Haber Institute, Max Planck Society, ou_24021              
2Dipartimento di Chimica, Università di Roma "La Sapienza", 1-00185 Rome, Italy, ou_persistent22              

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 Abstract: The process of intercalation is thermodynamically analyzed. It is shown that an ionic and an electronic component of the intercalation free energy can be distinguished. A prediction of the electronic contribution is possible if the electronic band structure of the host material in the energy range above the Fermi energy is known. An experimental way for measuring the electronic contribution is suggested.

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Language(s): eng - English
 Dates: 1994-09
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1149/1.2055115
 Degree: -

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Title: Journal of the Electrochemical Society
  Abbreviation : J. Electrochem. Soc.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: New York, NY, USA : Electrochemical Society
Pages: 4 Volume / Issue: 141 (9) Sequence Number: - Start / End Page: 2297 - 2300 Identifier: ISSN: 0013-4651
CoNE: https://pure.mpg.de/cone/journals/resource/991042748197686