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  On the photopolymerization of mevalonic lactone methacrylate : exposing the potential of an overlooked monomer

Esen, C., Antonietti, M., & Kumru, B. (2022). On the photopolymerization of mevalonic lactone methacrylate: exposing the potential of an overlooked monomer. Polymer Chemistry, 13(1), 139-146. doi:10.1039/D1PY01497H.

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 Creators:
Esen, Cansu1, Author              
Antonietti, Markus2, Author              
Kumru, Baris1, Author              
Affiliations:
1Baris Kumru, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_3202957              
2Markus Antonietti, Kolloidchemie, Max Planck Institute of Colloids and Interfaces, Max Planck Society, ou_1863321              

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 Abstract: Functional polymers remain at the core of polymer science in the second century of macromolecular material research. Lactones are known as monomers for ring-opening polymerizations; however, polymers containing lactone rings as pendant groups are rare. In this study, we revive an overlooked monomer, mevalonic lactone methacrylate, by demonstrating its radical polymerization, reporting the properties of the polymer product, and providing information on the thermal, UV, and hydrolytic stabilities of both the monomer and polymer. Controlled polymerization (via RAFT) provides synthetic precision and active terminal groups; thus, the formation of a simple block copolymer based on the aforementioned polymer is presented. The pendant ring accepts nucleophilic attacks, so the initially hydrophobic polymer can be altered to make it hydrophilic via reactions with nucleophiles in just seconds. Thus, the polymer film provides responsive surface formation.

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Language(s): eng - English
 Dates: 2021-11-292022
 Publication Status: Published in print
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 Rev. Type: -
 Identifiers: DOI: 10.1039/D1PY01497H
BibTex Citekey: D1PY01497H
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Title: Polymer Chemistry
  Abbreviation : Polym. Chem.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 13 (1) Sequence Number: - Start / End Page: 139 - 146 Identifier: ISSN: 1759-9954