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Schlagwörter:
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Zusammenfassung:
The clean Au{100} surface is known to be reconstructed, forming a pseudohexagonal (5×27) outermost layer. This structure is observed both in ultrahigh vacuum (UHV) and in the electrochemical environment at potentials corresponding to small negative surface electronic charges. Using a UHV scanning tunneling microscope (STM) at 77 K we have observed that the reconstruction can be lifted at large positive sample biases. The 20% less dense bulk‐terminated surface is produced and the excess material appears as irregularly shaped gold clusters. Over a period of a few minutes, however, the surface relaxes back to the pseudo‐hexagonal phase, a process that can also be followed with the STM.
