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  SnBrP-A SnIP-type representative in the Sn-Br-P system

Reiter, F., Pielmeier, M., Vogel, A., Jandl, C., Plodinec, M., Rohner, C., et al. (2022). SnBrP-A SnIP-type representative in the Sn-Br-P system. Zeitschrift für anorganische und allgemeine Chemie, e202100347. doi:10.1002/zaac.202100347.

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Zeitschrift anorg allge chemie - 2022 - Reiter - SnBrP%u2010A SnIP%u2010type representative in the Sn Br P system.pdf (Publisher version), 8MB
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Zeitschrift anorg allge chemie - 2022 - Reiter - SnBrP%u2010A SnIP%u2010type representative in the Sn Br P system.pdf
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 Creators:
Reiter, Felix1, Author
Pielmeier, Markus1, Author
Vogel, Anna1, Author
Jandl, Christian1, Author
Plodinec, Milivoj2, Author              
Rohner, Christian2, Author              
Lunkenbein, Thomas2, Author              
Nisi, Katharina3, Author
Holleitner, Alexander3, Author
Nilges, Tom1, Author
Affiliations:
1Tech Univ Munich, Dept Chem, Lichtenbergstr 4, D-85747 Munich, Germany, ou_persistent22              
2Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
3Tech Univ Munich, Walter Schottky & Phys Dept, Coulombwall 4a, D-85748 Garching, Germany, ou_persistent22              

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 Abstract: One-dimensional semiconductors are interesting materials due to their unique structural features and anisotropy, which grant them intriguing optical, dielectric and mechanical properties. In this work, we report on SnBrP, a lighter homologue of the first inorganic double helix compound SnIP. This class of compounds is characterized by intriguing mechanical and electronic properties, featuring a high flexibility without modulation of physical properties. Semiconducting SnBrP can be synthesized from red phosphorus, tin and tin(II)bromide at elevated temperatures and crystallizes as red-orange, cleavable needles. Raman measurements pointed towards a double helical building unit in SnBrP, showing similarities to the SnIP structure. After taking PL measurements, HR-TEM, and quantum chemical calculations into account, we were able to propose a sense full structure model for SnBrP.

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Language(s): eng - English
 Dates: 2021-12-212021-11-152022-01-07
 Publication Status: Published online
 Pages: 13
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/zaac.202100347
 Degree: -

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Title: Zeitschrift für anorganische und allgemeine Chemie
  Abbreviation : Z. Anorg. Allg. Chem.
Source Genre: Journal
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Publ. Info: Leipzig, Weinheim : Verlag Johann Ambrosius Barth / Wiley-VCH
Pages: 13 Volume / Issue: - Sequence Number: e202100347 Start / End Page: - Identifier: Other: 1521-3749
ISSN: 0044-2313
CoNE: https://pure.mpg.de/cone/journals/resource/954925453895