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  A Ferrotoroidic Candidate with Well-Separated Spin Chains

Zhang, J., Wang, X., Zhou, L., Liu, G., Adroja, D. T., da Silva, I., et al. (2022). A Ferrotoroidic Candidate with Well-Separated Spin Chains. Advanced Materials, 2106728, pp. 1-8. doi:10.1002/adma.202106728.

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 Creators:
Zhang, Jun1, Author
Wang, Xiancheng1, Author
Zhou, Long1, Author
Liu, Guangxiu1, Author
Adroja, Devashibhai T.1, Author
da Silva, Ivan1, Author
Demmel, Franz1, Author
Khalyavin, Dmitry1, Author
Sannigrahi, Jhuma1, Author
Nair, Hari S.1, Author
Duan, Lei1, Author
Zhao, Jianfa1, Author
Deng, Zheng1, Author
Yu, Runze1, Author
Shen, Xi1, Author
Yu, Richeng1, Author
Zhao, Hui1, Author
Zhao, Jimin1, Author
Long, Youwen1, Author
Hu, Zhiwei2, Author              
Lin, Hong-Ji1, AuthorChan, Ting-Shan1, AuthorChen, Chien-Te1, AuthorWu, Wei1, AuthorJin, Changqing1, Author more..
Affiliations:
1External Organizations, ou_persistent22              
2Zhiwei Hu, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863461              

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 Abstract: The search of novel quasi-1D materials is one of the important aspects in the field of material science. Toroidal moment, the order parameter of ferrotoroidic order, can be generated by a head-to-tail configuration of magnetic moment. It has been theoretically proposed that 1D dimerized and antiferromagnetic (AFM)-like spin chain hosts ferrotoroidicity and has the toroidal moment composed of only two antiparallel spins. Here, the authors report a ferrotoroidic candidate of Ba6Cr2S10 with such a theoretical model of spin chain. The structure consists of unique dimerized face-sharing CrS6 octahedral chains along the c axis. An AFM-like ordering at approximate to 10 K breaks both space- and time-reversal symmetries and the magnetic point group of mm ' 2 ' allows three ferroic orders in Ba6Cr2S10: (anti)ferromagnetic, ferroelectric, and ferrotoroidic orders. Their investigation reveals that Ba6Cr2S10 is a rare ferrotoroid ic candidate with quasi 1D spin chain, which can be considered as a starting point for the further exploration of the physics and applications of ferrotoroidicity.

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Language(s): eng - English
 Dates: 2022-01-212022-01-21
 Publication Status: Published in print
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000754082500001
DOI: 10.1002/adma.202106728
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Title: Advanced Materials
  Other : Adv. Mater.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: - Sequence Number: 2106728 Start / End Page: 1 - 8 Identifier: ISSN: 0935-9648
CoNE: https://pure.mpg.de/cone/journals/resource/954925570855