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  V+ (d4) and V2+ (d3) ion states in CdTe evidenced by photoluminescence

Peka, P., Selber, H., Schulz, H.-J., Schwarz, R., & Benz, K. W. (1996). V+ (d4) and V2+ (d3) ion states in CdTe evidenced by photoluminescence. Solid State Communications, 98(8), 677-682. doi:10.1016/0038-1098(96)00112-3.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000A-12D6-0 Version Permalink: https://hdl.handle.net/21.11116/0000-000A-7E2F-6
Genre: Journal Article

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 Creators:
Peka, Pavel1, 2, Author           
Selber, Heiko3, Author           
Schulz, Hans-Joachim3, Author           
Schwarz, R.4, 5, Author
Benz, K. W.4, Author
Affiliations:
1Fritz Haber Institute, Max Planck Society, ou_24021              
2Czech Technical University in Prague, Brehová 7, CZ-11519 Prague, ou_persistent22              
3Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
4Kristallographisches Institut der Universität Freiburg, Hebelstr. 25, D-79104 Freiburg, Germany, ou_persistent22              
5Physics Department, Univ. of Durham, England, ou_persistent22              

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 Abstract: High-resistivity CdTe:V crystals are investigated by photo-luminescence in the infrared spectral region. In addition to the known 3T2(F)→
3A2(F) emission of V3+ near 4100 cm−1, two further luminescence bands are detected at lower energies. A band peaking at 3450 cm−1 is assigned to the 4T2(F) →
4T1(F) transition of V2+ and a strong luminescence near 2780 cm−1 is identified as the 5E(D) →
5T2(D) emission of V+. These results are compared to other vanadium-doped II–VI compounds. A clear general trend of the transition energy with the band gap energy is deduced.

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Language(s): eng - English
 Dates: 1996-01-291996-02-201996-05-08
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0038-1098(96)00112-3
 Degree: -

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Title: Solid State Communications
  Abbreviation : Solid State Commun.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: New York : Pergamon
Pages: 6 Volume / Issue: 98 (8) Sequence Number: - Start / End Page: 677 - 682 Identifier: ISSN: 0038-1098
CoNE: https://pure.mpg.de/cone/journals/resource/954925445695