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  Ruthenium-C60 compounds: properties and catalytic potential

Wohlers, M., Herzog, B., Belz, T., Bauer, A., Braun, T., Rühle, T., et al. (1996). Ruthenium-C60 compounds: properties and catalytic potential. Synthetic Metals, 77(1-3), 55-58. doi:10.1016/0379-6779(96)80057-9.

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Genre: Journal Article

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 Creators:
Wohlers, Michael1, Author           
Herzog, Bernhard2, Author           
Belz, Thilo1, Author           
Bauer, Andrea1, Author           
Braun, Thomas1, Author           
Rühle, Thomas1, Author           
Schlögl, Robert1, Author           
Affiliations:
1Inorganic Chemistry, Fritz Haber Institute, Max Planck Society, ou_24023              
2Fritz Haber Institute, Max Planck Society, ou_24021              

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 Abstract: Ruthenium-C60 compounds were prepared by reaction of Ru3(CO)12 with C60 in refluxing toluene. The resulting compounds were found to be insoluble air-stable solids which consist of an amorphous matrix embedding small ruthenium metal particles of an average size of 2–5 nm. Furthermore, the presence of unreacted C60, small amounts of toluene and a residual CO-ligand sphere in ruthenium-C60 was found. The catalytic activity of ruthenium-C60 compounds at different temperatures was shown in prototype reactions like the liquid-phase hydrogenation of cyclohexene at 300 K or the hydrogenation of CO in the Fischer-Tropsch synthesis at 500 K.

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Language(s): eng - English
 Dates: 1996-02
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/0379-6779(96)80057-9
 Degree: -

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Title: Synthetic Metals
  Other : Synth. Met.
Source Genre: Journal
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Publ. Info: Lausanne : Elsevier
Pages: 4 Volume / Issue: 77 (1-3) Sequence Number: - Start / End Page: 55 - 58 Identifier: ISSN: 0379-6779
CoNE: https://pure.mpg.de/cone/journals/resource/954925528862