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  Comparing London dispersion pnictogen–π interactions in naphthyl-substituted dipnictanes

Gehlhaar, A., Schiavo, E., Wölper, C., Schulte, Y., Auer, A. A., & Schulz, S. (2022). Comparing London dispersion pnictogen–π interactions in naphthyl-substituted dipnictanes. Dalton Transactions, 51(13), 5016-5023. doi:10.1039/D2DT00477A.

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 Creators:
Gehlhaar, Alexander1, Author
Schiavo, Eduardo2, Author              
Wölper, Christoph1, Author
Schulte, Yannick1, Author
Auer, Alexander A.2, Author              
Schulz, Stephan1, 3, Author
Affiliations:
1Institute for Inorganic Chemistry, University of Duisburg-Essen, Universitätsstraße 5-7, D-45117 Essen, Germany, ou_persistent22              
2Research Group Auer, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2541705              
3Center for Nanointegration Duisburg-Essen (Cenide), University of Duisburg-Essen, Germany, ou_persistent22              

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 Abstract: Using a combination of NMR, single crystal X-ray diffraction (sc-XRD) and quantum chemistry, the structure-directing role of London Dispersion (LD) is demonstrated for dibismuthane Bi2Naph2 (1). 1 shows intermolecular Bi⋯π contacts in the solid-state, while π⋯π interactions as observed in the lighter homologues are missing. Comparison of the whole series of dipnictanes revealed the influence of the pnictogen atom on the strength of London dispersion and highlights its importance in heavy main group element chemistry.

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Language(s): eng - English
 Dates: 2022-02-152022-03-012022-04-07
 Publication Status: Published in print
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1039/D2DT00477A
 Degree: -

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Title: Dalton Transactions
  Abbreviation : Dalton Trans.
Source Genre: Journal
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Publ. Info: Cambridge, UK : Royal Society of Chemistry
Pages: - Volume / Issue: 51 (13) Sequence Number: - Start / End Page: 5016 - 5023 Identifier: ISSN: 1477-9226
CoNE: https://pure.mpg.de/cone/journals/resource/954925269323