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  Formation and Cleavage of a Sb−Sb Double Bond: From Carbene-Coordinated Distibenes to Stibinidenes

Krüger, J., Wölper, C., Auer, A. A., & Schulz, S. (2022). Formation and Cleavage of a Sb−Sb Double Bond: From Carbene-Coordinated Distibenes to Stibinidenes. European Journal of Inorganic Chemistry, 2022(3): e202100960. doi:10.1002/ejic.202100960.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000A-2C3E-1 Version Permalink: https://hdl.handle.net/21.11116/0000-000A-FF6F-C
Genre: Journal Article

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 Creators:
Krüger, Julia1, Author
Wölper, Christoph1, Author
Auer, Alexander A.2, Author           
Schulz, Stephan1, Author
Affiliations:
1Institute of Inorganic Chemistry and Center for Nanointegration Duisburg-Essen (CENIDE), University of Duisburg-Essen, Universitätsstraße 5–7, 45141 Essen, Germany, ou_persistent22              
2Research Group Auer, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2541705              

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Free keywords: Antimony; Density functional calculations; Distibene; Stibinidene; Structure elucidation
 Abstract: Stibine [L(Cl)Ga]2SbCl reacts with N-heterocyclic carbenes RNHCMe to either RNHCMe-coordinated distibenes L(Cl)Ga]SbSb(RNHCMe)Ga(Cl)L ((RNHCMe=Me, Et, i-Pr) or stibinidenes L(Cl)GaSb-RNHCMe (RNHCMe=Me, Et) after Sb−Sb bond cleavage. Energies of the products and possible reaction intermediates were calculated by DFT methods.

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Language(s): eng - English
 Dates: 2011-11-082021-12-092021-12-092022-01-27
 Publication Status: Published in print
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/ejic.202100960
 Degree: -

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Title: European Journal of Inorganic Chemistry
  Abbreviation : Eur. J. Inorg. Chem.
Source Genre: Journal
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Publ. Info: Weinheim, Germany : Wiley-VCH
Pages: - Volume / Issue: 2022 (3) Sequence Number: e202100960 Start / End Page: - Identifier: ISSN: 1434-1948
CoNE: https://pure.mpg.de/cone/journals/resource/954926953810_1