[2.2](2,5)Pyrazinophanes: synthesis and molecular structure

Eiermann, Uwe; Krieger, Claus; Neugebauer, Franz A.; Staab, Heinz A.

doi:10.1016/S0040-4039(00)82146-2

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[2.2](2,5)Pyrazinophanes: synthesis and molecular structure

Eiermann, U., Krieger, C., Neugebauer, F. A., & Staab, H. A. (1988). [2.2](2,5)Pyrazinophanes: synthesis and molecular structure. Tetrahedron Letters, 29(30), 3655-3658. doi:10.1016/S0040-4039(00)82146-2.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000A-5543-B Version Permalink: https://hdl.handle.net/21.11116/0000-000A-5544-A

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TetrahedronLett_29_1988_3655.pdf (Any fulltext), 226KB

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Creators:
Eiermann, Uwe¹, Author
Krieger, Claus¹, Author
Neugebauer, Franz A.¹, Author
Staab, Heinz A.¹, Author

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1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706

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Abstract: The pseudoortho (4a) and the pseudogeminal [2.2](2,5)pyrazinophane (4b) have been synthesized via 1,6-Hofmann elimination of [(5-methyl-2-pyrazinyl)methyl]trimethylammonium hydroxide (2b) and dimerization of the generated 2,5-dihydro-2,5-bis(methylene)pyrazine (3). The molecular structures of both isomers, 4a and 4b were determined by X-ray analysis.

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Language(s): eng - English

Dates: Submitted: 1988-05-28Date issued: 1988

Publication Status: Issued

Pages: 4

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Identifiers: DOI: 10.1016/S0040-4039(00)82146-2

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Title: Tetrahedron Letters

Abbreviation : Tetrahedron Lett.

Source Genre: Journal

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Publ. Info: Oxford : Pergamon

Pages: - Volume / Issue: 29 (30) Sequence Number: - Start / End Page: 3655 - 3658 Identifier: ISSN: 0040-4039
CoNE: https://pure.mpg.de/cone/journals/resource/954925448772