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  Proximity effects in the mass spectra of bis(dimethylamino)arenes, III, intramolecular cyclization of 2,2′-bis(dimethylamino)biphenylsunder electron impact

Rentzea, M., Höne, M., & Staab, H. A. (1988). Proximity effects in the mass spectra of bis(dimethylamino)arenes, III, intramolecular cyclization of 2,2′-bis(dimethylamino)biphenylsunder electron impact. Tetrahedron Letters, 29(44), 5633-5636. doi:10.1016/S0040-4039(00)80831-X.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000A-5665-4 Version Permalink: https://hdl.handle.net/21.11116/0000-000A-5666-3
Genre: Journal Article

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TetrahedronLett_29_1988_3655.pdf (Any fulltext), 226KB
 
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Rentzea, Marina1, Author           
Höne, Matthias1, Author           
Staab, Heinz A.1, Author           
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1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              

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 Abstract: There are not only strongly crowded “proton sponges” that show characteristic [M-Me2NH-H]+ peaks corresponding to cyclization to stable, even electron heterocyclic ions under EI. Fragmentation of title compounds which are moderately strong, not very crowded bases also leads to abundant [M-Me2NH-H]+ phenanthridinium ions, as shown by linked scans, exact mass measurements, MS/MS and collisionally activated dissociation (CAD) mass spectra.

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Language(s): eng - English
 Dates: 1988-08-101988
 Publication Status: Issued
 Pages: 4
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/S0040-4039(00)80831-X
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Title: Tetrahedron Letters
  Abbreviation : Tetrahedron Lett.
Source Genre: Journal
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Publ. Info: Oxford : Pergamon
Pages: - Volume / Issue: 29 (44) Sequence Number: - Start / End Page: 5633 - 5636 Identifier: ISSN: 0040-4039
CoNE: https://pure.mpg.de/cone/journals/resource/954925448772