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Zusammenfassung:
High-temperature diffusion affects the long-term stability of superalloys and hence their service life. Yet, details of the mechanisms remain elusive. Here, the γ-γʹ microstructure itself is used as a nanoscale diffusion couple to study the diffusion of alloying elements within narrow and wide γ channels during annealing for up to 100 h at 750 °C in a nickel-based superalloy. Predictions from thermodynamic and kinetic calculations are compared to near-atomic experimental measurements as a function of the γ channel width. An overlooked width-dependence of compositional evolution is revealed that may directly affect the microstructural and compositional predictions of service life of nickel-based superalloys.
