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  Structures of Quino[7,8-h ]quinoline and Quino[8,7-h ]quinoline

Krieger, C., Newsom, I., Zirnstein, M. A., & Staab, H. A. (1989). Structures of Quino[7,8-h ]quinoline and Quino[8,7-h ]quinoline. Angewandte Chemie International Edition, 28(1), 84-86. doi:10.1002/anie.198900841.

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AngewChemIntEd_28_1989_84.pdf (Any fulltext), 316KB
 
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 Creators:
Krieger, Claus1, Author           
Newsom, Ian1, Author           
Zirnstein, Michael A.1, Author           
Staab, Heinz A.1, Author           
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1Department of Organic Chemistry, Max Planck Institute for Medical Research, Max Planck Society, ou_1497706              

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 Abstract: The two title compounds 1 and 2 are almost planar in the crystalline state. The decades-old uncertainties concerning the synthesis and structural assignment have now been resolved by X-ray structure analyses of the two compounds. A striking feature in the case of the extremely strongly and also kinetically active base 1 is the large central external angle of the “naphthalene unit” (125.4°), which results in a relatively large N ⃛N distance of 272.8 pm.

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Language(s): eng - English
 Dates: 1988-08-181989-01
 Publication Status: Issued
 Pages: 3
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.198900841
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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 28 (1) Sequence Number: - Start / End Page: 84 - 86 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851