Chemical Activity of Thin Oxide Layers: Strong Interactions with the Support 
Yield a New Thin-Film Phase of ZnO

Schott, Vadim; Oberhofer, Harald; Birkner, Alexander; Xu, Mingchun; Wang, Yuemin; Muhler, Martin; Reuter, Karsten; Wöll, Christof

doi:10.1002/anie.201302315

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Chemical Activity of Thin Oxide Layers: Strong Interactions with the Support Yield a New Thin-Film Phase of ZnO

Schott, V., Oberhofer, H., Birkner, A., Xu, M., Wang, Y., Muhler, M., et al. (2013). Chemical Activity of Thin Oxide Layers: Strong Interactions with the Support Yield a New Thin-Film Phase of ZnO. Angewandte Chemie International Edition, 52(45), 11925-11929. doi:10.1002/anie.201302315.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000A-CF99-1 Version Permalink: https://hdl.handle.net/21.11116/0000-000D-47A2-C

Genre: Journal Article

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Creators:
Schott, Vadim¹, Author
Oberhofer, Harald², Author
Birkner, Alexander¹, Author
Xu, Mingchun¹, Author
Wang, Yuemin^{1, 3}, Author
Muhler, Martin³, Author
Reuter, Karsten², Author
Wöll, Christof⁴, Author

Affiliations:
1Chair of Physical Chemistry, Ruhr-University, Bochum (Germany), ou_persistent22
2Chair for Theoretical Chemistry, Catalysis Research Center, Technische Universität München, ou_persistent22
3Laboratory of Technical Chemistry, Ruhr-University, Bochum (Germany), ou_persistent22
4Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany), ou_persistent22

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Abstract: Metal substrates affect the chemical properties of ZnO layers, which are important catalyst materials for the industrial production of methanol through the oxidation of CO. Interactions with the substrate lead to the formation of a new, planar ZnO thin-film phase, in which less highly oxidized Zn atoms bind CO more strongly than the Zn atoms in the normal wurtzite modification.

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Language(s): eng - English

Dates: Modified: 2013-06-19Submitted: 2013-03-19Published Online: 2013-10-28Date issued: 2013-11-04

Publication Status: Issued

Pages: 5

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Table of Contents: -

Rev. Type: Peer

Identifiers: DOI: 10.1002/anie.201302315

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Title: Angewandte Chemie International Edition

Abbreviation : Angew. Chem., Int. Ed.

Source Genre: Journal

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Publ. Info: Weinheim : Wiley-VCH

Pages: 5 Volume / Issue: 52 (45) Sequence Number: - Start / End Page: 11925 - 11929 Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851