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  New Sr9Os5O23, Made Up of Quasi 1D and 2D Fragments of the Perovskite Structure

Thakur, G. S., Doert, T., & Jansen, M. (2022). New Sr9Os5O23, Made Up of Quasi 1D and 2D Fragments of the Perovskite Structure. Crystal Growth & Design, 1-8. doi:10.1021/acs.cgd.2c00705.

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 Creators:
Thakur, Gohil S.1, Author           
Doert, Thomas2, Author
Jansen, Martin2, Author
Affiliations:
1Inorganic Chemistry, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863425              
2External Organizations, ou_persistent22              

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 Abstract: Sr9Os5O23, a new strontium osmate, has been synthesized as a coarse-crystalline material from SrO2 and Os, in a SrCl2 flux. It crystallizes in a rather large monoclinic cell with space group, C2/c. It is a member of a newly identified homologous series Sr2n-1OsnO5n-2 of compounds with n = 3, 5, 7,middotmiddotmiddot. The crystal structure consists of stacks of two-dimensional slabs of perovskite-type layers alternating with one-dimensional zigzag chains of corner sharing OsO6 octahedra. The (Os5+/6+) mixed valence title compound shows an antiferromagnetic-like transition at T-N similar to 75 K, as inferred from magnetic susceptibility data.

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Language(s): eng - English
 Dates: 2022-08-042022-08-04
 Publication Status: Published in print
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 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000837854200001
DOI: 10.1021/acs.cgd.2c00705
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Title: Crystal Growth & Design
  Other : Cryst. Growth Des.
Source Genre: Journal
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Publ. Info: Washington, DC : American Chemical Society
Pages: - Volume / Issue: - Sequence Number: - Start / End Page: 1 - 8 Identifier: ISSN: 1528-7483
CoNE: https://pure.mpg.de/cone/journals/resource/110978984570353