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  Surface-template assembly of two-dimensional metal-organic coordination networks

Stepanow, S., Lin, N., Barth, J. V., & Kern, K. (2006). Surface-template assembly of two-dimensional metal-organic coordination networks. Journal of Physical Chemistry B, 110(46), 23472-23477.

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 Creators:
Stepanow, S.1, Author           
Lin, N.1, Author           
Barth, J. V.1, 2, Author           
Kern, K.1, Author           
Affiliations:
1Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370481              
2Former Research Groups, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370500              

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 Abstract: The self-assembly of iron-coordinated two-dimensional metal-organic
networks on a Cu(100) surface has been investigated by scanning
tunneling microscopy under ultra-high-vacuum conditions. We applied
three rodlike polybenzene dicarboxylic acid molecules with different
backbone lengths as organic linkers. The three linker molecules form
topologically identical rectangular networks with Fe, all comprising
iron pairs as the network nodes. Whereas the length of the linker
molecules defines the dimension of the networks, the substrate also
significantly influences the structural details, e. g., network
orientation with respect to the substrate, geometric shape of the
network cavities, Fe-carboxylate coordination configuration, and
iron-iron distance.

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Language(s): eng - English
 Dates: 2006
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 305981
ISI: 000242045900077
 Degree: -

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Title: Journal of Physical Chemistry B
Source Genre: Journal
 Creator(s):
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Publ. Info: -
Pages: - Volume / Issue: 110 (46) Sequence Number: - Start / End Page: 23472 - 23477 Identifier: ISSN: 1520-6106