Design of extended surface-supported chiral metal-organic arrays comprising 
mononuclear iron centers

Dmitriev, A.; Spillmann, H.; Lingenfelder, M.; Lin, N.; Barth, J. V.; Kern, K.

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Design of extended surface-supported chiral metal-organic arrays comprising mononuclear iron centers

Dmitriev, A., Spillmann, H., Lingenfelder, M., Lin, N., Barth, J. V., & Kern, K. (2004). Design of extended surface-supported chiral metal-organic arrays comprising mononuclear iron centers. Langmuir, 20(12), 4799-4801.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-FED0-9 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-FED1-8

Genre: Journal Article

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Creators:
Dmitriev, A.¹, Author
Spillmann, H.¹, Author
Lingenfelder, M.¹, Author
Lin, N.¹, Author
Barth, J. V.^{1, 2}, Author
Kern, K.¹, Author

Affiliations:
1Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370481
2Former Research Groups, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370500

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Abstract: A design strategy for fabricating a surface-supported chiral
metal-organic system comprising a regular arrangement of mononuclear
iron centers and nanocavities is presented. By sequential deposition of
1,2,4-benzenetricarboxylic acid (tmla) molecules and iron atoms on a
Cu(100) surface under ultrahigh vacuum conditions, chiral square-planar
Fe(tmla)(4) metal-organic complexes are generated, which order in
extended homochiral arrays. Structure formation and envisioned
functionality of such metal-organic architectures are discussed.

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Language(s): eng - English

Dates: Date issued: 2004

Publication Status: Issued

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Identifiers: eDoc: 192953
ISI: 000221846000004

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Title: Langmuir

Source Genre: Journal

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Pages: - Volume / Issue: 20 (12) Sequence Number: - Start / End Page: 4799 - 4801 Identifier: ISSN: 0743-7463