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Schlagwörter:
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Zusammenfassung:
A design strategy for fabricating a surface-supported chiral
metal-organic system comprising a regular arrangement of mononuclear
iron centers and nanocavities is presented. By sequential deposition of
1,2,4-benzenetricarboxylic acid (tmla) molecules and iron atoms on a
Cu(100) surface under ultrahigh vacuum conditions, chiral square-planar
Fe(tmla)(4) metal-organic complexes are generated, which order in
extended homochiral arrays. Structure formation and envisioned
functionality of such metal-organic architectures are discussed.