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  Evidence for C60 dimerisation in the fulleride [Cr(C9H12)2]+C60-

Hönnerscheid, A., van Wüllen, L., Dinnebier, R. E., Jansen, M., Rahmer, J., & Mehring, M. (2004). Evidence for C60 dimerisation in the fulleride [Cr(C9H12)2]+C60-. Physical Chemistry Chemical Physics, 6(9), 2454-2460.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-FE84-F Version Permalink: https://hdl.handle.net/21.11116/0000-000E-FE85-E
Genre: Journal Article

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 Creators:
Hönnerscheid, A.1, Author           
van Wüllen, L.1, Author           
Dinnebier, R. E.2, Author           
Jansen, M.1, Author           
Rahmer, J., Author
Mehring, M., Author
Affiliations:
1Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370503              
2Scientific Facility X-Ray Diffraction (Robert E. Dinnebier), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370494              

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 Abstract: We report a detailed study of the structure, dynamics and electronic
structure of the new fulleride [Cr(C9H12)(2)]-(+)-C-60(-). Using a
variety of characterization tools including EPR, NMR, SQUID magnetic
measurements and high resolution X-ray powder diffraction a spin
pairing of the C-60(-) spins with decreasing temperatures could be
observed. Contrary to the observed phase transition of first order in
the related compound [Cr(C6H9)(2)]C-+(60)- the phase transition
observed in the title compound is of higher order.

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Language(s): eng - English
 Dates: 2004
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: -
 Identifiers: eDoc: 192959
ISI: 000221886100080
 Degree: -

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Title: Physical Chemistry Chemical Physics
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 6 (9) Sequence Number: - Start / End Page: 2454 - 2460 Identifier: ISSN: 1463-9076