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  The bis(maleonitriledithiolato)zincate(II) complex of the monoprotonated 4,4'-bipyridine cation

Xu, H., Xie, J. L., Ren, X.-M., & Chen, Y. C. (2002). The bis(maleonitriledithiolato)zincate(II) complex of the monoprotonated 4,4'-bipyridine cation. Acta Crystallographica E, 58, M750-M752.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-EE1D-7 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-EE1E-6
Genre: Journal Article

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 Creators:
Xu, H., Author
Xie, J. L., Author
Ren, X.-M.1, Author           
Chen, Y. C., Author
Affiliations:
1Former Scientific Facilities, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370501              

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 Abstract: In the title salt, (C10H9N2)(2) [Zn(C4N2S2)(2)].C2H3N or [4,4'-
bipyH][Zn(mnt)(2)].C2H3N, where mnt(2-) denotes
maleonitriledithiolate and 4,4'-bipyH is monoprotonated 4,4'-
bipyridine, the Zn-II ion is tetrahedrally surrounded by four S
atoms of two mnt(2-) ligands. The counter-cations, 4,4'-
bipyH(+), form one-dimensional chains through strong
(pyridine)N- H...N(pyridine) hydrogen-bonding interactions.
Anions and cations stack in alternating layers which are nearly
parallel to the bc plane of the crystallographic unit cell.

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Language(s): eng - English
 Dates: 2002
 Publication Status: Issued
 Pages: -
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 7014
ISI: 000180890600020
 Degree: -

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Title: Acta Crystallographica E
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: -
Pages: - Volume / Issue: 58 Sequence Number: - Start / End Page: M750 - M752 Identifier: ISSN: 1600-5368