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  Compressibility of CO intercalated C60 crystals

van Smaalen, S., Dinnebier, R. E., Milletich, R., Kunz, M., Holleman, I., von Helden, G., et al. (2000). Compressibility of CO intercalated C60 crystals. Chemical Physics Letters, 319(3-4), 283-286. doi:10.1016/S0009-2614(00)00096-8.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000B-6AEC-5 Version Permalink: https://hdl.handle.net/21.11116/0000-000B-6AED-4
Genre: Journal Article

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 Creators:
van Smaalen, Sander, Author
Dinnebier, Robert E., Author
Milletich, Ronald, Author
Kunz, Martin, Author
Holleman, Iwan, Author
von Helden, Gert, Author
Meijer, Gerard1, Author           
Affiliations:
1Department of Molecular and Laser Physics, University of Nijmegen, ou_persistent22              

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 Abstract: We report the pressure dependence of the cubic lattice parameter of (CO)xC60 at different temperatures, as determined by X-ray powder diffraction. In the measured range of pressures from 0.2 to 2 GPa, the volume is found to depend linearly on the pressure. The extrapolated volume bulk modulus of the ordered phase at room temperature is found to be K0=-VdP/dV=31.5(5) GPa. The bulk modulus at T=150 K is found as K0=26.9(5) GPa. The greater stiffness at higher temperature is explained by the entropic contribution of the CO molecules to the bulk modulus.

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Language(s): eng - English
 Dates: 2000-01-061999-09-212000-03-172000-03-17
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1016/S0009-2614(00)00096-8
 Degree: -

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Title: Chemical Physics Letters
  Other : Chem. Phys. Lett.
Source Genre: Journal
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Publ. Info: Amsterdam : North-Holland
Pages: 4 Volume / Issue: 319 (3-4) Sequence Number: - Start / End Page: 283 - 286 Identifier: ISSN: 0009-2614
CoNE: https://pure.mpg.de/cone/journals/resource/954925389241