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  Infrared spectroscopy of jet-cooled neutral and ionized aniline-Ar

Piest, H., von Helden, G., & Meijer, G. (1999). Infrared spectroscopy of jet-cooled neutral and ionized aniline-Ar. The Journal of Chemical Physics, 110(4), 2010-2015. doi:10.1063/1.477866.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000B-6B05-8 Version Permalink: https://hdl.handle.net/21.11116/0000-000B-6B06-7
Genre: Journal Article

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1.477866.pdf (Publisher version), 681KB
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1999
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 Creators:
Piest, Hans, Author
von Helden, Gert, Author
Meijer, Gerard1, 2, Author           
Affiliations:
1Department of Molecular and Laser Physics, University of Nijmegen, ou_persistent22              
2FOM Institute for Plasmaphysics Rijnhuizen, ou_persistent22              

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 Abstract: We report the infrared (IR) absorption spectrum of the jet-cooled neutral aniline–Ar Van der Waals complex together with that of the aniline–Ar cation in the 350–1700 cm−1 range. The spectra are measured using mass-selective ion detection in two different IR–ultraviolet double-resonance excitation schemes, using a free-electron laser as a source of widely tunable, intense IR radiation. A comparison with calculated IR spectra of the bare neutral aniline and of the cation of aniline allows for an unambiguous assignment of all the observed modes. The dissociation limit of the neutral aniline–Ar complex is bracketed between 273 and 329 cm−1,


significantly lower than previously estimated.

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Language(s): eng - English
 Dates: 1998-09-231998-10-231999-01-121999-01-22
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.477866
 Degree: -

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Title: The Journal of Chemical Physics
  Abbreviation : J. Chem. Phys.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Institute of Physics
Pages: 6 Volume / Issue: 110 (4) Sequence Number: - Start / End Page: 2010 - 2015 Identifier: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226