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  A reanalysis of the k3π state of CO

Berden, G., Jongma, R. T., van der Zande, D., & Meijer, G. (1997). A reanalysis of the k3π state of CO. The Journal of Chemical Physics, 107(20), 8303-8310. doi:10.1063/1.475031.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000B-643D-1 Version Permalink: https://hdl.handle.net/21.11116/0000-000B-643E-0
Genre: Journal Article

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1.475031.pdf (Publisher version), 739KB
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1997
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 Creators:
Berden, Giel, Author
Jongma, Rienk T., Author
van der Zande, Dorien, Author
Meijer, Gerard1, Author           
Affiliations:
1Department of Molecular and Laser Physics, University of Nijmegen, ou_persistent22              

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 Abstract: The k3π state of the CO molecule is investigated in the region between 91 000 and 97 000 cm−1 via 1+1 resonance enhanced multiphoton ionization spectroscopy on CO molecules prepared in a single quantum level of the a3π(v=1) state. A new vibronic band is found which is at lower energy than the vibrational ground state reported in the literature, leading to a reassignment of the vibrational numbering of the k3π state. The rotationally resolved spectra of the k3π (v=0–6)←a3π(v=1, J=1, Ω=1) of 12CO and 13CO have been observed and analyzed, confirming the new vibrational labeling and providing a full set of molecular constants of the k3π valence state.

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Language(s): eng - English
 Dates: 1997-07-221997-08-211997-11-22
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.475031
 Degree: -

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Title: The Journal of Chemical Physics
  Abbreviation : J. Chem. Phys.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Institute of Physics
Pages: 8 Volume / Issue: 107 (20) Sequence Number: - Start / End Page: 8303 - 8310 Identifier: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226