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Abstract:
We here theoretically outline and experimentally demonstrate that polarization spectroscopy can be combined with cavity ring down (CRD) spectroscopy, thereby retaining the specific advantages of both techniques. The b1Σ+g(v′=2)←X3Σ⎯g(v′′=0) transition of molecular oxygen around 628 nm is used to demonstrate the possibility to selectively measure either the polarization-dependent absorption or the resonant magneto-optical rotation of gas-phase molecules in the appropriate setup. Just as in CRD absorption spectroscopy, where the rate of absorption is measured, in the here presented polarization-dependent CRD (PDCRD) detection scheme the rate of polarization rotation is measured, which enables the polarization rotation to be quantitatively determined. Apart from studying electro-optic and magneto-optic phenomena on gas-phase species, the PDCRD detection scheme is demonstrated to be applicable to the study of magneto-optical rotation in transparent solid samples as well.
