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  Rovibrational Motion of CO in Solid C60

Holleman, I., von Helden, G., Olthof, E. H. T., van Bentum, P. J. M., Engeln, R., Nachtegaal, G. H., et al. (1997). Rovibrational Motion of CO in Solid C60. Physical Review Letters, 79(6), 1138-1141. doi:10.1103/PhysRevLett.79.1138.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000B-660F-3 Version Permalink: https://hdl.handle.net/21.11116/0000-000B-6610-0
Genre: Journal Article

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PhysRevLett.79.1138.pdf (Publisher version), 158KB
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1997
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APS
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 Creators:
Holleman, I., Author
von Helden, G., Author
Olthof, E. H. T., Author
van Bentum, P. J. M., Author
Engeln, R., Author
Nachtegaal, G. H., Author
Kentgens, A. P. M., Author
Meier, B. H., Author
van der Avoird, A., Author
Meijer, Gerard1, Author           
Affiliations:
1Department of Molecular and Laser Physics, University of Nijmegen, ou_persistent22              

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 Abstract: Solid C60 can be intercalated with CO gas in a 1:1 ratio. The rovibrational motion of CO in these samples is studied as a function of temperature by IR and NMR spectroscopy. The observed spectra indicate a gradual transition from nearly free motion of CO at room temperature to hindered motion at low temperature, with only tunneling between symmetry equivalent orientations remaining. The observations are augmented by theory, and details on the local environment of the CO molecules are extracted.

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Language(s): eng - English
 Dates: 1997-04-241997-08-11
 Publication Status: Published in print
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1103/PhysRevLett.79.1138
 Degree: -

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Title: Physical Review Letters
  Abbreviation : Phys. Rev. Lett.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Physical Society
Pages: 4 Volume / Issue: 79 (6) Sequence Number: - Start / End Page: 1138 - 1141 Identifier: ISSN: 0031-9007
CoNE: https://pure.mpg.de/cone/journals/resource/954925433406_1