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  High Rydberg states of DABCO: Spectroscopy, ionization potential, and comparison with mass analyzed threshold ionization

Boogaarts, M. G. H., Holleman, I., Jongma, R. T., Parker, D. H., Meijer, G., & Even, U. (1996). High Rydberg states of DABCO: Spectroscopy, ionization potential, and comparison with mass analyzed threshold ionization. The Journal of Chemical Physics, 104(12), 4357-4364. doi:10.1063/1.471186.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000C-1560-0 Version Permalink: https://hdl.handle.net/21.11116/0000-000C-1569-7
Genre: Journal Article

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1.471186.pdf (Publisher version), 376KB
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Copyright Date:
1996
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 Creators:
Boogaarts, Maarten G. H., Author
Holleman, Iwan, Author
Jongma, Rienk T., Author
Parker, David H., Author
Meijer, Gerard1, Author           
Even, Uzi, Author
Affiliations:
1Department of Molecular and Laser Physics, University of Nijmegen, ou_persistent22              

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 Abstract: Doubly‐resonant excitation/vibrational autoionization is used to accurately determine the ionization potential (IP) of the highly symmetric caged amine 1,4 diazabicyclo[2,2,2]octane (DABCO). The IP of DABCO excited with one quantum of the ν24(e′) vibration lies at (59 048.62±0.03) cm−1, based on fitting 56 components of the npxyRydberg series (δ=0.406±0.002) to the Rydberg formula. Rydberg state transition energies and linewidths are determined using standard calibration and linefitting techniques. The IP determined from Rydberg state extrapolation is compared with that determined by mass analyzed threshold ionization (MATI). Effects of static electric fields on MATI signals measured for the high Rydberg states are discussed.

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Language(s): eng - English
 Dates: 1995-08-081995-12-061998-06-041996-03-22
 Publication Status: Issued
 Pages: 8
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.471186
 Degree: -

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Title: The Journal of Chemical Physics
  Abbreviation : J. Chem. Phys.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Institute of Physics
Pages: 8 Volume / Issue: 104 (12) Sequence Number: - Start / End Page: 4357 - 4364 Identifier: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226