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Abstract:
Research on endohedral fullerenes has yielded unambiguous evidence for the existence of selected inside-the-cage complexes. Milligram quantities of purified samples of metallofullerenes have been produced, and characterized via techniques that selectively probe the endohedral guest. Experiments aimed at a detailed understanding of the molecular properties of the endohedral complexes as well as of the material properties of compounds containing endohedral fullerenes have just started.