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  Rotational ordering transition in single-crystal C60 studied by Raman spectroscopy

van Loosdrecht, P. H. M., van Bentum, P. J. M., & Meijer, G. (1992). Rotational ordering transition in single-crystal C60 studied by Raman spectroscopy. Physical Review Letters, 68(8), 1176-1179. doi:10.1103/PhysRevLett.68.1176.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000C-3E80-E Version Permalink: https://hdl.handle.net/21.11116/0000-000C-3E84-A
Genre: Journal Article

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PhysRevLett.68.1176.pdf (Publisher version), 194KB
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1992
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 Creators:
van Loosdrecht, P. H. M., Author
van Bentum, P. J. M., Author
Meijer, Gerard1, Author           
Affiliations:
1University of Nijmegen, ou_persistent22              

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 Abstract: Raman spectroscopic data are presented on the rotational ordering fcc→sc transition in single-crystal C60. Splittings and activation of new modes reveal the influence of the cubic structure, and are in agreement with the crystal symmetry in both phases. The temperature dependence of the spectra is consistent with a sharp first-order phase transition near 252 K. A simple model is proposed for the explanation of the temperature dependence of the spectra, involving a large vibrational-rotational coupling in the fcc phase, and essentially no rotational disorder in the sc phase.

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Language(s): eng - English
 Dates: 1991-11-271992-02-24
 Publication Status: Issued
 Pages: 4
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1103/PhysRevLett.68.1176
 Degree: -

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Title: Physical Review Letters
  Abbreviation : Phys. Rev. Lett.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Physical Society
Pages: 4 Volume / Issue: 68 (8) Sequence Number: - Start / End Page: 1176 - 1179 Identifier: ISSN: 0031-9007
CoNE: https://pure.mpg.de/cone/journals/resource/954925433406_1