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  Laser desorption jet-cooling spectroscopy of the benzoic acid monomer

Meijer, G., Vries, M. S. D., Hunziker, H. E., & Wendt, H. R. (1990). Laser desorption jet-cooling spectroscopy of the benzoic acid monomer. The Journal of Physical Chemistry, 94(11), 4394-4396. doi:10.1021/j100374a006.

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 Creators:
Meijer, Gerard1, Author           
Vries, Mattanjah S. De, Author
Hunziker, Heinrich E., Author
Wendt, H. Russell., Author
Affiliations:
1IBM Almaden Research Center, ou_persistent22              

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 Abstract: Laser desorption followed by jet cooling has been used to produce an intense beam of internally cooled benzoic acid monomers. As a result, the S1 ← S0 gas-phase absorption spectrum of the jet-cooled benzoic acid monomer could be identified for the first time. Delayed ionization out of a triplet state, populated by rapid S1→ T intersystem crossing, followed by mass-selective detection of the parent ions is performed. The spectral lines have a Lorentzian shape with a line width of 6.5 cm-1, corresponding to an intersystem crossing rate of 1.2 x 1012 s-1.

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Language(s): eng - English
 Dates: 1990-03-051990-05-01
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1021/j100374a006
 Degree: -

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Title: The Journal of Physical Chemistry
  Abbreviation : J. Phys. Chem.
Source Genre: Journal
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Publ. Info: Washington, D.C. : American Chemical Society
Pages: 3 Volume / Issue: 94 (11) Sequence Number: - Start / End Page: 4394 - 4396 Identifier: ISSN: 1932-7447
CoNE: https://pure.mpg.de/cone/journals/resource/954926947766_3