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  Experimental Determination of the Dissociative Recombination Rate Coefficient for Rotationally Cold CH+ and Its Implications for Diffuse Cloud Chemistry

Paul, D., Grieser, M., Grussie, F., von Hahn, R., Isberner, L. W., Kálosi, Á., et al. (2022). Experimental Determination of the Dissociative Recombination Rate Coefficient for Rotationally Cold CH+ and Its Implications for Diffuse Cloud Chemistry. The Astrophysical Journal, 939(2): 122. doi:10.3847/1538-4357/ac8e02.

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2208.14927.pdf (Preprint), 933KB
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 Urheber:
Paul, Daniel1, Autor           
Grieser, Manfred1, Autor           
Grussie, Florian1, Autor           
von Hahn, Robert1, Autor           
Isberner, Leonard W., Autor
Kálosi, Ábel, Autor
Krantz, Claude1, Autor           
Kreckel, Holger2, Autor           
Müll, Damian1, Autor           
Neufeld, David A., Autor
Savin, Daniel W., Autor
Schippers, Stefan, Autor
Wilhelm, Patrick1, Autor           
Wolf, Andreas1, Autor           
Wolfire, Mark G., Autor
Novotný, Oldřich1, Autor           
Affiliations:
1Division Prof. Dr. Klaus Blaum, MPI for Nuclear Physics, Max Planck Society, ou_904548              
2Holger Kreckel, ASTROLAB - MPG-Gruppe im Anschluss an ERC Starting Grant, MPI for Nuclear Physics, Max Planck Society, ou_3349435              

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Schlagwörter: Astrophysics, Galaxy Astrophysics, astro-ph.GA, Astrophysics, Instrumentation and Methods for Astrophysics, astro-ph.IM
 MPINP: Quantendynamik - Abteilung Blaum
 MPINP: Expt. CSR - Abteilung Blaum
 Zusammenfassung: Observations of CH+ are used to trace the physical properties of diffuse clouds, but this requires an accurate understanding of the underlying CH+ chemistry. Until this work, the most uncertain reaction in that chemistry was dissociative recombination (DR) of CH+. Using an electron–ion merged-beams experiment at the Cryogenic Storage Ring, we have determined the DR rate coefficient of the CH+ electronic, vibrational, and rotational ground state applicable for different diffuse cloud conditions. Our results reduce the previously unrecognized order-of-magnitude uncertainty in the CH+ DR rate coefficient to ∼20% and are applicable at all temperatures relevant to diffuse clouds, ranging from quiescent gas to gas locally heated by processes such as shocks and turbulence. Based on a simple chemical network, we find that DR can be an important destruction mechanism at temperatures relevant to quiescent gas. As the temperature increases locally, DR can continue to be important up to temperatures of ∼600 K, if there is also a corresponding increase in the electron fraction of the gas. Our new CH+ DR rate-coefficient data will increase the reliability of future studies of diffuse cloud physical properties via CH+ abundance observations.

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 Datum: 2022-11-14
 Publikationsstatus: Online veröffentlicht
 Seiten: Main paper: PDFLaTeX with 7 pages, 3 figures. Appendix starting on page 7: PDFLaTeX with 11 pages, 2 figures, 4 tables. This article has been accepted by The Astrophysical Journal
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 Identifikatoren: arXiv: 2208.14927
DOI: 10.3847/1538-4357/ac8e02
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Titel: The Astrophysical Journal
Genre der Quelle: Zeitschrift
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Ort, Verlag, Ausgabe: Bristol; Vienna : IOP Publishing; IAEA
Seiten: - Band / Heft: 939 (2) Artikelnummer: 122 Start- / Endseite: - Identifikator: ISSN: 0004-637X
CoNE: https://pure.mpg.de/cone/journals/resource/954922828215_3