High-resolution spectroscopy on the Ã1B1 (0, 6, 0) ←X̃1A1(0, 0, 0) transition 
in SiCl2

Meijer, Gerard; Heinze, Johannes; Meerts, W. Leo; Meulen, J.J ter; T Hougen, Jon

doi:10.1016/0022-2852(89)90115-X

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High-resolution spectroscopy on the Ã¹B₁ (0, 6, 0) ←X̃¹A₁(0, 0, 0) transition in SiCl₂

Meijer, G., Heinze, J., Meerts, W. L., Meulen, J. t., & T Hougen, J. (1989). High-resolution spectroscopy on the Ã¹B₁ (0, 6, 0) ←X̃¹A₁(0, 0, 0) transition in SiCl₂. Journal of Molecular Spectroscopy, 138(1), 251-263. doi:10.1016/0022-2852(89)90115-X.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000C-3C3A-1 Version Permalink: https://hdl.handle.net/21.11116/0000-000C-3C3B-0

Genre: Journal Article

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Creators:
Meijer, Gerard^{1, 2}, Author
Heinze, Johannes, Author
Meerts, W. Leo, Author
Meulen, J.J ter, Author
T Hougen, Jon, Author

Affiliations:
1IBM Almaden Research Center, ou_persistent22
2University of Nijmegen, ou_persistent22

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Abstract: High-resolution laser-induced fluorescence spectra of Si³⁵Cl₂ and Si³⁵Cl³⁷Cl have been observed in a molecular beam. A spectral resolution of 8 MHz was obtained on the Ã¹B₁ (0, 6, 0) ←X̃¹A₁(0, 0, 0) transition around 323 nm, which allowed the dense rotational structure of this electronic transition to be completely resolved. The rotational constants in the Ã¹B₁ (0, 6, 0) state reflect the almost 22° opening of the ClSiCl bond angle on going from X̃ to Ã, whereas the Si-Cl bond length decreases slightly.

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Language(s): eng - English

Dates: Submitted: 1989-03-16Date issued: 1989-11

Publication Status: Issued

Pages: 13

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Table of Contents: -

Rev. Type: Peer

Identifiers: DOI: 10.1016/0022-2852(89)90115-X

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Title: Journal of Molecular Spectroscopy

Other : J. Mol. Spectrosc.

Abbreviation : JMS

Source Genre: Journal

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Publ. Info: Elsevier B. V.

Pages: 13 Volume / Issue: 138 (1) Sequence Number: - Start / End Page: 251 - 263 Identifier: ISSN: 0022-2852
CoNE: https://pure.mpg.de/cone/journals/resource/954922646043