English
 
Help Privacy Policy Disclaimer
  Advanced SearchBrowse

Item

ITEM ACTIONSEXPORT
Add to Basket
 Local TagsRelease HistoryDetailsSummary
  Copper Complexes with Diazoolefin Ligands and their Photochemical Conversion into Alkenylidene Complexes

Kooji, B., Varava, P., Fadaei-Tirani, F., Scopelliti, R., Pantazis, D. A., Van Trieste III, G. P., et al. (2023). Copper Complexes with Diazoolefin Ligands and their Photochemical Conversion into Alkenylidene Complexes. Angewandte Chemie International Edition, 62(4): e202214899. doi:10.1002/anie.202214899.

Item is

 

show all hide all

Basic

show hide
Item Permalink: https://hdl.handle.net/21.11116/0000-000C-1BE0-9 Version Permalink: https://hdl.handle.net/21.11116/0000-000C-8253-3
Genre: Journal Article

Files

show Files

Locators

show

Creators

show
hide
 Creators:
Kooji, Bastiaan1, Author
Varava, Paul1, Author
Fadaei-Tirani, Farzaneh1, Author
Scopelliti, Rosario1, Author
Pantazis, Dimitrios A.2, Author           
Van Trieste III, Gerard P.3, Author
Powers, David C.3, Author
Severin, Kay1, Author
Affiliations:
1Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland, ou_persistent22              
2Research Group Pantazis, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2541711              
3Department of Chemistry, Texas A&M University, College Station, TX 77843 USA, ou_persistent22              

Content

show
hide
Free keywords: Alkenylidene; Carbene; Copper; Diazo Compounds; Organometallic Chemistry
 Abstract: Homometallic copper complexes with alkenylidene ligands are discussed as intermediates in catalysis but the isolation of such complexes has remained elusive. Herein, we report the structural characterization of copper complexes with bridging and terminal alkenylidene ligands. The compounds were obtained by irradiation of CuI complexes with N-heterocyclic diazoolefin ligands. The complex with a terminal alkenylidene ligand required isolation in a crystalline matrix, and its structural characterization was enabled by in crystallo photolysis at low temperature.

Details

show
hide
Language(s): eng - English
 Dates: 2022-10-102022-11-292023-01-23
 Publication Status: Issued
 Pages: 5
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.202214899
 Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

show
hide
Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem. Int. Ed.
Source Genre: Journal
 Creator(s):
Affiliations:
Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 62 (4) Sequence Number: e202214899 Start / End Page: - Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851