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  High-pressure high-temperature preparation of CeGe3

Clark, W. P., Ueltzen, K., Burkhardt, U., Akselrud, L., Grin, Y., & Schwarz, U. (2023). High-pressure high-temperature preparation of CeGe3. Zeitschrift für Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 78(3-4), 189-193. doi:10.1515/znb-2023-0306.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000C-DA42-4 Version Permalink: https://hdl.handle.net/21.11116/0000-000D-2FDA-A
Genre: Journal Article

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 Creators:
Clark, William P.1, Author           
Ueltzen, Katharina1, Author           
Burkhardt, Ulrich2, Author           
Akselrud, Lev1, Author           
Grin, Yuri3, Author           
Schwarz, Ulrich4, Author           
Affiliations:
1Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863405              
2Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
3Juri Grin, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863413              
4Ulrich Schwarz, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863423              

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 Abstract: The metastable compound CeGe3 was obtained by high-pressure high-temperature synthesis from pre-reacted Ce and Ge at 3 GPa of pressure and 1873 K, with subsequent annealing over several hours at 1173 K. The product crystallises in a 2 × 2 × 2 superstructure of the cubic Cu3Au-type structure with space group F m 3 m and a = 8.6970(2) Å. CeGe3 decomposes at 520(10) K into CeGe2-x and elemental Ge. © 2023 the author(s), published by De Gruyter, Berlin/Boston 2023.

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Language(s): eng - English
 Dates: 2023-03-082023-03-08
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: -
 Identifiers: DOI: 10.1515/znb-2023-0306
BibTex Citekey: Clark2023
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Title: Zeitschrift für Naturforschung, Teil B: Anorganische Chemie, Organische Chemie
  Abbreviation : Z. Naturforsch., B: Anorg. Chem., Org. Chem.
Source Genre: Journal
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Publ. Info: Tübingen : Verlag der Zeitschrift für Naturforschung
Pages: - Volume / Issue: 78 (3-4) Sequence Number: - Start / End Page: 189 - 193 Identifier: CoNE: https://pure.mpg.de/cone/journals/resource/ISSN 0340-5087