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  Practical Aspects of Thermal Dissociation and Recombination Reactions: the Reaction Systems CF3X(+M)<-> CF3+X (+M) with X=F, Cl, Br, and I

Cobos, C. J., Tellbach, E., Sölter, L., & Troe, J. (2023). Practical Aspects of Thermal Dissociation and Recombination Reactions: the Reaction Systems CF3X(+M)<-> CF3+X (+M) with X=F, Cl, Br, and I. Israel Journal of Chemistry, in press. doi:10.1002/ijch.202300006.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000C-F5EE-4 Version Permalink: https://hdl.handle.net/21.11116/0000-000C-F5F5-B
Genre: Journal Article
Other : Practical Aspects of Thermal Dissociation and Recombination Reactions: the Reaction Systems CF3X(+M)↔CF3+X (+M) with X=F, Cl, Br, and I
Other : Practical Aspects of Thermal Dissociation and Recombination Reactions: the Reaction Systems CF3X(+M)<-> CF3+X (+M) with X=F, Cl, Br, and I

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Israel Journal of Chemistry - 2023 - Cobos.pdf (Postprint), 4MB
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Israel Journal of Chemistry - 2023 - Cobos.pdf
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2023-03-14
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 Creators:
Cobos, Carlos Jorge, Author
Tellbach, Elsa1, Author           
Sölter, Lars1, Author           
Troe, Jürgen1, Author           
Affiliations:
1Emeritus Group Spectroscopy and Photochemical Kinetics, Max Planck Institute for Multidisciplinary Sciences, Max Planck Society, ou_3371542              

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 Abstract: The thermal dissociation/recombination reactions of the perfluoromethyl halides CF4↔CF3+F, CF3Cl↔CF3+Cl, CF3Br↔CF3+Br, and CF3I↔CF3+I are analyzed with respect to their transition (for increasing pressures) from second-order to first-order dissociation (or from third-order to second-order recombination). The dependence of this transition on the temperature is documented. Practical aspects of the modelling of falloff curves are discussed.

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Language(s): eng - English
 Dates: 2023-03-14
 Publication Status: Published online
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/ijch.202300006
 Degree: -

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Project name : Support by the Deutsche Forschungsgemeinschaft (Project TR69/21-3) is also gratefully acknowledged
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Title: Israel Journal of Chemistry
  Other : Isr. J. Chem.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH Verlag GmbH & Co. KGaA
Pages: - Volume / Issue: - Sequence Number: in press Start / End Page: - Identifier: ISSN: 0021-2148
CoNE: https://pure.mpg.de/cone/journals/resource/954925408770