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Zusammenfassung:
In practical applications of inkjet printing the nozzles in a printhead have intermittent idle periods, during which ink can evaporate from the nozzle exit. Inks are usually multicomponent where each compo-nent has its own characteristic evaporation rate resulting in concentration gradients within the ink. These gradients may directly and indirectly (via Marangoni flows) alter the jetting process and thereby its repro-ducibility and the resulting print quality. In the present work we study selective evaporation from an inkjet nozzle for water-glycerol mixtures. Through experiments, analytical modeling, and numerical simulations, we investigate changes in mixture composition with drying time. By monitoring the acoustics within the printhead, and subsequently modeling the system as a mass-spring-damper system, the composition of the mixture can be obtained as a function of drying time. The results from the analytical model are val-idated using numerical simulations of the full fluid mechanical equations governing the printhead flows and pressure fields. Furthermore, the numerical simulations reveal that the time-independent concentra-tion gradient we observe in the experiments is due to the steady state of water flux through the printhead. Finally, we measure the number of drop formation events required in this system before the mixture con-centration within the nozzle attains the initial (predrying) value, and find a stronger than exponential trend in the number of drop formations required. These results shed light on the complex physiochemical hydro-dynamics associated with the drying of ink at a printhead nozzle, and help in increasing the stability and reproducibility of inkjet printing.