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  Brønsted Acid Catalyzed Asymmetric Silylation of Biaryl Diols

Han, J. T., Zhou, H., & List, B. (2023). Brønsted Acid Catalyzed Asymmetric Silylation of Biaryl Diols. Synlett, 34(20), 2393-2395. doi:10.1055/a-2100-1575.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000D-56F9-A Version Permalink: https://hdl.handle.net/21.11116/0000-000E-346D-E
Genre: Journal Article

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 Creators:
Han, Jung Tae1, Author           
Zhou, Hui1, Author           
List, Benjamin1, Author           
Affiliations:
1Research Department List, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445585              

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Free keywords: Brønsted acid; imidodiphosphorimidate; silylation; axial chirality; desymmetrization; kinetic resolution
 Abstract: We report a Brønsted acid catalyzed enantioselective silylation of biaryl diols with an allylsilane as silicon source. This process enables facile access to enantioenriched biaryl silyl ethers with an axial stereogenicity. A control experiment supports a mechanism proceeding by desymmetrization followed by kinetic resolution.

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Language(s): eng - English
 Dates: 2023-04-302023-05-232023-05-252023-12-15
 Publication Status: Issued
 Pages: 3
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1055/a-2100-1575
 Degree: -

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Title: Synlett
  Abbreviation : Synlett
Source Genre: Journal
 Creator(s):
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Publ. Info: Stuttgart : Georg Thieme Verlag
Pages: - Volume / Issue: 34 (20) Sequence Number: - Start / End Page: 2393 - 2395 Identifier: ISSN: 0936-5214
CoNE: https://pure.mpg.de/cone/journals/resource/954925570856