Catalytic hydroxylation of arylthianthrenium salts with nitrous oxide

Ni, Shengyang; Cornella, Josep

doi:10.1016/j.tet.2023.133602

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Catalytic hydroxylation of arylthianthrenium salts with nitrous oxide

Ni, S., & Cornella, J. (2023). Catalytic hydroxylation of arylthianthrenium salts with nitrous oxide. Tetrahedron, 145: 133602. doi:10.1016/j.tet.2023.133602.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000D-BD74-C Version Permalink: https://hdl.handle.net/21.11116/0000-000D-BD75-B

Genre: Journal Article

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Creators:
Ni, Shengyang¹, Author
Cornella, Josep¹, Author

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1Research Group Cornellà, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2466693

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Abstract: We present a catalytic protocol for the conversion of aryl thianthrenium salts to the corresponding phenols, by means of a nickel catalyst and N₂O. The method tolerates various functional groups and permits the hydroxylaiton of functionalized molecules. Capitalizing on the high selectivity in the introduction of the thianthrene unit in aryl groups, the method represents a formal hydroxylation of aromatic C–H bonds.

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Language(s): eng - English

Dates: Submitted: 2023-06-13Accepted: 2023-08-12Published Online: 2023-08-23Date issued: 2023-09-25

Publication Status: Issued

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Rev. Type: Peer

Identifiers: DOI: 10.1016/j.tet.2023.133602

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Title: Tetrahedron

Abbreviation : Tetrahedron

Source Genre: Journal

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Publ. Info: Kidlington : Elsevier Science

Pages: - Volume / Issue: 145 Sequence Number: 133602 Start / End Page: - Identifier: ISSN: 0040-4020
CoNE: https://pure.mpg.de/cone/journals/resource/00404020