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  Synthesis and Characterization of the Double Perovskite Y2MgRuO6

Rößler, S., Burkhardt, U., Tjeng, L. H., & Komarek, A. C. (2023). Synthesis and Characterization of the Double Perovskite Y2MgRuO6. Crystals, 13(9): 1365, pp. 1-9. doi:10.3390/cryst13091365.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000D-C8B6-4 Version Permalink: https://hdl.handle.net/21.11116/0000-000D-C8B8-2
Genre: Journal Article

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 Creators:
Rößler, Sahana1, Author           
Burkhardt, Ulrich2, Author           
Tjeng, Liu H.3, Author           
Komarek, Alexander C.4, Author           
Affiliations:
1Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863445              
2Ulrich Burkhardt, Chemical Metal Science, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863422              
3Liu Hao Tjeng, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863452              
4Alexander Komarek, Physics of Correlated Matter, Max Planck Institute for Chemical Physics of Solids, Max Planck Society, ou_1863446              

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 Abstract: A new double perovskite compound with nominal composition Y (Formula presented.) MgRuO (Formula presented.) is synthesized by the floating zone technique. X-ray diffraction measurements reveal a monoclinic crystal structure with space group (Formula presented.) and monoclinic angle (Formula presented.) = 90.178(1) (Formula presented.) as crystallographically expected for a double perovskite. A composition of Y (Formula presented.) Mg (Formula presented.) Ru (Formula presented.) O (Formula presented.) is revealed by our single crystal X-ray diffraction measurement. The magnetic susceptibility of this compound does not show indications of magnetic ordering down to the lowest temperature. A Curie–Weiss fit for the paramagnetic part above 300 K yields an effective moment that indicates an S = 1 Ru (Formula presented.) state. We attribute the occurrence of the S = 1 state and the lack of magnetic order to the presence of the (Formula presented.) -site disorder. © 2023 by the authors.

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Language(s): eng - English
 Dates: 2023-09-112023-09-11
 Publication Status: Issued
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 Rev. Type: -
 Identifiers: DOI: 10.3390/cryst13091365
BibTex Citekey: Rößler2023
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Title: Crystals
Source Genre: Journal
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Publ. Info: Basel, Switzerland : MDPI AG
Pages: - Volume / Issue: 13 (9) Sequence Number: 1365 Start / End Page: 1 - 9 Identifier: ISSN: 2073-4352
CoNE: https://pure.mpg.de/cone/journals/resource/2073-4352