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  Mode softening, precursor phenomena, and intermediate phases in PbZrO3

Ko, J. H., Gorny, M., Majchrowski, A., Roleder, K., & Bussmann-Holder, A. (2013). Mode softening, precursor phenomena, and intermediate phases in PbZrO3. Physical Review B, 87(18): 184110.

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 Creators:
Ko, J. H., Author
Gorny, M., Author
Majchrowski, A., Author
Roleder, K., Author
Bussmann-Holder, A.1, 2, 3, 4, Author           
Affiliations:
1Former Departments, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370502              
2Department Electronic Structure Theory (Ali Alavi), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370479              
3Department Physical Chemistry of Solids (Joachim Maier), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370483              
4Department Nanochemistry (Bettina V. Lotsch), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370482              

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 Abstract: Single crystals of PbZrO3 have been studied by Brillouin light scattering, birefringence, and piezoelectric coefficient measurements. The structural phase transition at T-c is shown to be related to the softening of a longitudinal acoustic (LA) mode, whereas precursor effects are deduced from a central peak in the light scattering spectrum, finite birefringence, and piezoelectric coefficient above the structural instability. An intermediate phase in the vicinity of T-c is apparent where a coexistence of the LA mode with a high frequency mode appears, and in addition the transverse acoustic (TA) mode becomes visible.

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Language(s): eng - English
 Dates: 2013
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: Internal
 Identifiers: eDoc: 672280
ISI: 000319056900002
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Title: Physical Review B
Source Genre: Journal
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Pages: - Volume / Issue: 87 (18) Sequence Number: 184110 Start / End Page: - Identifier: ISSN: 1098-0121