Synthesis and Crystal Structures of the Alkali Aluminium Thiohypodiphosphates MI
AlP2S6 (M = Li, Na)

Kuhn, A.; Eger, R.; Nuss, J.; Lotsch, B. V.

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Synthesis and Crystal Structures of the Alkali Aluminium Thiohypodiphosphates M^IAlP₂S₆ (M = Li, Na)

Kuhn, A., Eger, R., Nuss, J., & Lotsch, B. V. (2013). Synthesis and Crystal Structures of the Alkali Aluminium Thiohypodiphosphates M^IAlP₂S₆ (M = Li, Na). Zeitschrift für anorganische und allgemeine Chemie, 639, 1087-1089.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-C57D-8 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-C57E-7

Genre: Journal Article

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Creators:
Kuhn, A., Author
Eger, R.^{1, 2}, Author
Nuss, J.^{3, 4}, Author
Lotsch, B. V.¹, Author

Affiliations:
1Department Nanochemistry (Bettina V. Lotsch), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370482
2Former Departments, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370502
3Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370503
4Department Quantum Materials (Hidenori Takagi), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370487

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Abstract: The crystal structures of the alkali aluminium thiohypodiphosphates MIAlP2S6 (MI = Li, Na) are reported. NaAlP2S6 crystallizes in the orthorhombic space group Fdd2 (no. 43) with a = 8.0400(2), b = 10.9452(2), c = 20.8801(4) angstrom, and V = 1837.44(7) angstrom 3 (Z = 8). It is isostructural with AgAlP2S6, which is consistent with the similar ionic radii of Na and Ag. In contrast, LiAlP2S6 crystallizes in a different structure type which has not been observed in the large number of thiohypodiphosphates reported so far. It crystallizes in the monoclinic space group C2/c (no. 15) with a = 6.783(3), b = 10.365(4), c = 11.776(4) angstrom, = 94.399(5)degrees, and V = 825.46(5) angstrom 3 (Z = 4).

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Language(s): eng - English

Dates: Date issued: 2013

Publication Status: Issued

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Rev. Type: Internal

Identifiers: eDoc: 672294
ISI: 000320173800004

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Title: Zeitschrift für anorganische und allgemeine Chemie

Source Genre: Journal

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Pages: - Volume / Issue: 639 Sequence Number: - Start / End Page: 1087 - 1089 Identifier: ISSN: 0044-2313