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  Double-Icosahedral Li Clusters in a New Binary Compound Ba19Li44: A Reinvestigation of the Ba-Li Phase Diagram

Smetana, V., Babizhetskyy, V., Vajenine, G. V., Hoch, C., & Simon, A. (2007). Double-Icosahedral Li Clusters in a New Binary Compound Ba19Li44: A Reinvestigation of the Ba-Li Phase Diagram. Inorganic Chemistry, 46(13), 5425-5428.

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 Creators:
Smetana, V.1, 2, Author           
Babizhetskyy, V.1, 2, 3, Author           
Vajenine, G. V.1, Author           
Hoch, C.1, Author           
Simon, A.1, Author           
Affiliations:
1Former Departments, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370502              
2Department Nanochemistry (Bettina V. Lotsch), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370482              
3Department Quantum Materials (Hidenori Takagi), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370487              

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 Abstract: The binary Ba-Li system was reinvestigated for compositions with less than 80 at. % Li. A new compound, Ba19Li44, stable up to 126 degrees C, was found and structurally characterized. According to single-crystal X-ray diffraction data, the compound crystallizes in a new structure type with a tetragonal unit cell, space group I (4) over bar 2d, a = 16.3911(5) angstrom, c = 32.712(1) angstrom, Z = 4, and V = 8788.7(5) angstrom(3). It can be described as a complicated variant of the chalcopyrite structure. Typical for Li-rich phases, Ba19Li44 contains icosahedron-based polytetrahedral clusters.

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Language(s): eng - English
 Dates: 2007
 Publication Status: Issued
 Pages: -
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 Table of Contents: -
 Rev. Type: Peer
 Identifiers: eDoc: 338649
ISI: 000247304600044
 Degree: -

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Title: Inorganic Chemistry
Source Genre: Journal
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Pages: - Volume / Issue: 46 (13) Sequence Number: - Start / End Page: 5425 - 5428 Identifier: ISSN: 0020-1669