Intermediate valence behaviour of the ternary Cerium-Nickel-Phosphide, Ce2Ni12P7

Babizhetskyy, V.; Isnard, O.; Hiebl, K.

Local TagsRelease HistoryDetailsSummary

Intermediate valence behaviour of the ternary Cerium-Nickel-Phosphide, Ce₂Ni₁₂P₇

Babizhetskyy, V., Isnard, O., & Hiebl, K. (2007). Intermediate valence behaviour of the ternary Cerium-Nickel-Phosphide, Ce₂Ni₁₂P₇. Solid State Communications, 142(1-2), 80-84.

Item is Released

show all

Basic

hide

Item Permalink: https://hdl.handle.net/21.11116/0000-000E-B693-E Version Permalink: https://hdl.handle.net/21.11116/0000-000E-B694-D

Genre: Journal Article

Files

show Files

Locators

show

Creators

hide

Creators:
Babizhetskyy, V.^{1, 2, 3}, Author
Isnard, O., Author
Hiebl, K., Author

Affiliations:
1Department Quantum Materials (Hidenori Takagi), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370487
2Former Departments, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370502
3Department Nanochemistry (Bettina V. Lotsch), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370482

Content

hide

Free keywords: ternary cerium-nickel-phosphorous compound; X-ray absorption; magnetism; electrical transport

Abstract: The crystal structure of Ce2Ni12P7 (Zr2Fe12P7 type) was determined from X-ray powder diffraction data: full profile refinement, hexagonal unit cell, space group P(6) over bar, a = 9.1008(4) angstrom, c = 3.7362(1) angstrom, R-B = 0.026, R-p = 0.055. The results of the magnetic and electrical resistivity measurements indicate a strong f-d hybridization of the 4f electrons of the cerium atom. Analysis of X-ray absorption spectroscopy experiments proved these findings, and the Ce valence in this compound was derived as v = 3.23-3.21 at 10 K and room temperature, respectively. (C) 2007 Elsevier Ltd. All rights reserved.

Details

hide

Language(s): eng - English

Dates: Date issued: 2007

Publication Status: Issued

Pages: -

Publishing info: -

Table of Contents: -

Rev. Type: Peer

Identifiers: eDoc: 338552
ISI: 000245497500019

Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

hide

Title: Solid State Communications

Source Genre: Journal

Creator(s):

Affiliations:

Publ. Info: -

Pages: - Volume / Issue: 142 (1-2) Sequence Number: - Start / End Page: 80 - 84 Identifier: ISSN: 0038-1098