Possible existence off alkali metal orthocarbonates at high pressure

Čančarević, Ž.; Schön, J. C.; Jansen, M.

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Possible existence off alkali metal orthocarbonates at high pressure

Čančarević, Ž., Schön, J. C., & Jansen, M. (2007). Possible existence off alkali metal orthocarbonates at high pressure. Chemistry - A European Journal, 13(26), 7330-7348.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-B7D9-F Version Permalink: https://hdl.handle.net/21.11116/0000-000E-B7DA-E

Genre: Journal Article

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Creators:
Čančarević, Ž., Author
Schön, J. C.^{1, 2}, Author
Jansen, M.¹, Author

Affiliations:
1Abteilung Jansen, Former Departments, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370503
2Department Nanoscale Science (Klaus Kern), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370481

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Free keywords: alkali metal orthocarbonates; high pressure polymorphs; structure prediction

Abstract: We investigate the possible existence of crystalline alkali metal orthocarbonates, A(4)CO(4), where A=Li, Na, K, Rb, and Cs. We study the equilibrium between the possible modifications of the orthocarbonate A(4)CO(4) and the binary mixture of the possible modifications of the alkali oxide A(2)O and those of the alkali metal carbonate A(2)CO(3) as function of pressure. In all cases, the orthocarbonate should be stable at sufficiently high pressure ranging from 22-32 GPa (Rb4CO4) to 200-220 GPa (Cs4CO4).

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Language(s): eng - English

Dates: Date issued: 2007

Publication Status: Issued

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Rev. Type: Peer

Identifiers: eDoc: 338745
ISI: 000249570800006

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Title: Chemistry - A European Journal

Source Genre: Journal

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Pages: - Volume / Issue: 13 (26) Sequence Number: - Start / End Page: 7330 - 7348 Identifier: ISSN: 0947-6539