Synthesis and crystal structure of LiBa2N and identification of LiBa3N

Smetana, V.; Babizhetskyy, V.; Vajenine, G. V.; Simon, A.

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Synthesis and crystal structure of LiBa₂N and identification of LiBa₃N

Smetana, V., Babizhetskyy, V., Vajenine, G. V., & Simon, A. (2007). Synthesis and crystal structure of LiBa₂N and identification of LiBa₃N. Journal of Solid State Chemistry, 180(6), 1889-1893.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-B4D1-A Version Permalink: https://hdl.handle.net/21.11116/0000-000E-B4D2-9

Genre: Journal Article

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Creators:
Smetana, V.^{1, 2}, Author
Babizhetskyy, V.^{1, 2, 3}, Author
Vajenine, G. V.¹, Author
Simon, A.¹, Author

Affiliations:
1Former Departments, Max Planck Institute for Solid State Research, Max Planck Society, ou_3370502
2Department Nanochemistry (Bettina V. Lotsch), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370482
3Department Quantum Materials (Hidenori Takagi), Max Planck Institute for Solid State Research, Max Planck Society, ou_3370487

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Free keywords: submtride; barium; lithium; X-ray diffraction

Abstract: The metal-rich part of the Li-Ba-N system was investigated using powder and single-crystal X-ray diffraction analysis. The crystal structures of two new ternary subnitrides, LiBa2N and of LiBa3N, were determined from single-crystal and powder X-ray diffraction data, respectively, LiBa2N has a tetragonal structure (space group, P4(2)/nMC, Z = 8, a = 7.980(1), c = 14.263(2) angstrom). The structure contains infinite mutually perpendicular rows of edge-sharing LiBa5N octahedra. LiBa3N is isostructural with NaBa3N (P6(3)/mmc, Z = 2, a = 8.182(1), c = 6.922(4)angstrom). (c) 2007 Elsevier Inc. All rights reserved.

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Language(s): eng - English

Dates: Date issued: 2007

Publication Status: Issued

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Rev. Type: Peer

Identifiers: eDoc: 338694
ISI: 000248102100012

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Title: Journal of Solid State Chemistry

Source Genre: Journal

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Pages: - Volume / Issue: 180 (6) Sequence Number: - Start / End Page: 1889 - 1893 Identifier: ISSN: 0022-4596