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  Surface plasmon enhanced photochemistry: Mo(CO)6-Al-quartz

Wolf, M., Zhu, X., White, J. M., Koschmieder, T. H., & Thompson, J. C. (1992). Surface plasmon enhanced photochemistry: Mo(CO)6-Al-quartz. The Journal of Chemical Physics, 97(9), 7015-7016. doi:10.1063/1.463211.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-54B3-9 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-54B7-5
Genre: Journal Article

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7015_1_online.pdf (Publisher version), 604KB
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https://hdl.handle.net/21.11116/0000-000E-54B5-7
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Copyright Date:
1992
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AIP
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 Creators:
Wolf, Martin1, Author                 
Zhu, X.‐Y., Author
White, J. M., Author
Koschmieder, T. H., Author
Thompson, J. C., Author
Affiliations:
1Physical Chemistry, Fritz Haber Institute, Max Planck Society, ou_634546              

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 Abstract: We demonstrate that surface plasmon oscillations excited at an adsorbate covered metal–vacuum interface can effectively couple to the electronic system of the adsorbed molecule. Using p‐polarized light (hν=3.5 eV) incident at the surface plasmon resonant angle in Kretschmann’s attenuated‐total‐reflection (ATR) configuration, we observe a strong enhancement of the photodissociation rate of Mo(CO)6 from a 180 Å Al film, evaporated on a quartz prism in UHV.

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Language(s): eng - English
 Dates: 1992-05-151992-07-161992-11-01
 Publication Status: Issued
 Pages: 2
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1063/1.463211
 Degree: -

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Title: The Journal of Chemical Physics
  Abbreviation : J. Chem. Phys.
Source Genre: Journal
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Publ. Info: Woodbury, N.Y. : American Institute of Physics
Pages: 2 Volume / Issue: 97 (9) Sequence Number: - Start / End Page: 7015 - 7016 Identifier: ISSN: 0021-9606
CoNE: https://pure.mpg.de/cone/journals/resource/954922836226