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  Reductive Cross-Coupling of a Vinyl Thianthrenium Salt and Secondary Alkyl Iodides

Lansbergen, B., Tewari, S., Tomczyk, I., Seemann, M., Buchholz, H. L., Rippegarten, M., et al. (2023). Reductive Cross-Coupling of a Vinyl Thianthrenium Salt and Secondary Alkyl Iodides. Angewandte Chemie International Edition, 62(52): e202313659. doi:10.1002/anie.202313659.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000D-FBDB-2 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-3470-9
Genre: Journal Article

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 Creators:
Lansbergen, Beatrice1, Author           
Tewari, Srija1, Author           
Tomczyk, Ireneusz1, Author           
Seemann, Maik1, Author           
Buchholz, Henning Louis2, Author           
Rippegarten, Mike1, Author           
Chamier Cieminski, Daniel1, Author           
Juliá, Fabio1, Author           
Ritter, Tobias1, Author           
Affiliations:
1Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040308              
2Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589              

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Free keywords: Alkylation; Late Stage Functionalization; Reductive Electrophile Cross-Coupling; Vinyl Thianthrenium Salt
 Abstract: We report the first reductive vinylation of alkyl iodides. The reaction uses a vinyl thianthrenium salt, a palladium catalyst, and an alkyl zinc intermediate formed in situ to trap the LnPdII(vinyl) complex formed after oxidative addition before it undergoes undesired homocoupling to form butadiene.

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Language(s): eng - English
 Dates: 2023-09-132023-11-152023-12-21
 Publication Status: Issued
 Pages: 6
 Publishing info: -
 Table of Contents: -
 Rev. Type: Peer
 Identifiers: DOI: 10.1002/anie.202313659
 Degree: -

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Title: Angewandte Chemie International Edition
  Abbreviation : Angew. Chem., Int. Ed.
Source Genre: Journal
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Publ. Info: Weinheim : Wiley-VCH
Pages: - Volume / Issue: 62 (52) Sequence Number: e202313659 Start / End Page: - Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851