Reductive Cross-Coupling of a Vinyl Thianthrenium Salt and Secondary Alkyl 
Iodides

Lansbergen, Beatrice; Tewari, Srija; Tomczyk, Ireneusz; Seemann, Maik; Buchholz, Henning Louis; Rippegarten, Mike; Chamier Cieminski, Daniel; Juliá, Fabio; Ritter, Tobias

doi:10.1002/anie.202313659

Local TagsRelease HistoryDetailsSummary

Reductive Cross-Coupling of a Vinyl Thianthrenium Salt and Secondary Alkyl Iodides

Lansbergen, B., Tewari, S., Tomczyk, I., Seemann, M., Buchholz, H. L., Rippegarten, M., et al. (2023). Reductive Cross-Coupling of a Vinyl Thianthrenium Salt and Secondary Alkyl Iodides. Angewandte Chemie International Edition, 62(52): e202313659. doi:10.1002/anie.202313659.

Item is Released

show all

Basic

hide

Item Permalink: https://hdl.handle.net/21.11116/0000-000D-FBDB-2 Version Permalink: https://hdl.handle.net/21.11116/0000-000E-3470-9

Genre: Journal Article

Files

show Files

Locators

show

Creators

hide

Creators:
Lansbergen, Beatrice¹, Author
Tewari, Srija¹, Author
Tomczyk, Ireneusz¹, Author
Seemann, Maik¹, Author
Buchholz, Henning Louis², Author
Rippegarten, Mike¹, Author
Chamier Cieminski, Daniel¹, Author
Juliá, Fabio¹, Author
Ritter, Tobias¹, Author

Affiliations:
1Research Department Ritter, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_2040308
2Research Department Schüth, Max-Planck-Institut für Kohlenforschung, Max Planck Society, ou_1445589

Content

hide

Free keywords: Alkylation; Late Stage Functionalization; Reductive Electrophile Cross-Coupling; Vinyl Thianthrenium Salt

Abstract: We report the first reductive vinylation of alkyl iodides. The reaction uses a vinyl thianthrenium salt, a palladium catalyst, and an alkyl zinc intermediate formed in situ to trap the L_nPd^II(vinyl) complex formed after oxidative addition before it undergoes undesired homocoupling to form butadiene.

Details

hide

Language(s): eng - English

Dates: Submitted: 2023-09-13Published Online: 2023-11-15Date issued: 2023-12-21

Publication Status: Issued

Pages: 6

Publishing info: -

Table of Contents: -

Rev. Type: Peer

Identifiers: DOI: 10.1002/anie.202313659

Degree: -

Event

show

Legal Case

show

Project information

show

Source 1

hide

Title: Angewandte Chemie International Edition

Abbreviation : Angew. Chem., Int. Ed.

Source Genre: Journal

Creator(s):

Affiliations:

Publ. Info: Weinheim : Wiley-VCH

Pages: - Volume / Issue: 62 (52) Sequence Number: e202313659 Start / End Page: - Identifier: ISSN: 1433-7851
CoNE: https://pure.mpg.de/cone/journals/resource/1433-7851