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  Two organoantimony (V) coordination complexes modulated by isomers of trifluoromethylbenzoate ligands: Syntheses, crystal structure, photodegradation properties

Zhang, X.-Y., Cui, L.-s., Zhang, X., Jin, F., & Fan, Y.-H. (2017). Two organoantimony (V) coordination complexes modulated by isomers of trifluoromethylbenzoate ligands: Syntheses, crystal structure, photodegradation properties. JOURNAL OF MOLECULAR STRUCTURE, 1134, 742-750. doi:10.1016/j.molstruc.2017.01.039.

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Item Permalink: https://hdl.handle.net/21.11116/0000-000E-0CB3-B Version Permalink: https://hdl.handle.net/21.11116/0000-000E-0CB4-A
Genre: Journal Article

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https://doi.org/10.1016/j.molstruc.2017.01.039 (Publisher version)
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 Creators:
Zhang, Xiao-Yin1, Author
Cui, Lian-sheng1, Author
Zhang, Xia1, Author
Jin, Fan2, Author
Fan, Yu-Hua1, Author
Affiliations:
1external, ou_persistent22              
2Max Planck Institute for Terrestrial Microbiology, Max Planck Society, Karl-von-Frisch-Strasse 10, D-35043 Marburg, DE, ou_3135468              

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 Abstract: Two organoantimony (V) coordination complexes, namely Ph3Sb(2-tmbc) (1)
and Ph3Sb(3-tmbc) (2) (2-tmbc = 2-(trifluoromethyl)benzoic carboxyl,
3-tmbc = 3-(trifluoromethyl)benzoic carboxyl) have been synthesized and
characterized by IR spectra, elemental analysis, powder X-ray
diffraction (PXRD) and single-crystal X-ray diffraction. Single-crystal
X-ray diffraction analysis reveals that complexes 1 and 2 show different
architectures by the intermolecular hydrogen bonds (C-H center dot
center dot center dot F), complex 1 displays an 1D straight chain
structure, while complex 2 shows an 1D zigzag chain structure. The
photodegradation properties of complexes 1 and 2 has been investigated
in organic dyes (RhB, MV, MB) the results indicated that the two
complexes are good candidates for the photocatalytic degradation of
three dyes. The tentative photocatalytic degradations mechanism is
discussed. (C) 2017 Elsevier B.V. All rights reserved.

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 Dates: 2017-04-15
 Publication Status: Issued
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 Table of Contents: -
 Rev. Type: -
 Identifiers: ISI: 000394919100085
DOI: 10.1016/j.molstruc.2017.01.039
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Title: JOURNAL OF MOLECULAR STRUCTURE
Source Genre: Journal
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Pages: - Volume / Issue: 1134 Sequence Number: - Start / End Page: 742 - 750 Identifier: ISSN: 0022-2860